Chemical Composition
Organic substances such as lignin, pectin, hemicellulose and natural proteins that exist alongside pure cellulose within the plant structure define the chemical makeup of the flax fiber. These non-cellulosic components act as the binder that holds the fiber bundles together in the stem. Their presence distinguishes linen from cotton, which is almost entirely pure cellulose.
Structural Function
Pectins are particularly active as they govern the stiffness and the moisture absorption of the yarn. During the retting process, microbes consume a portion of these non-cellulosic components to release the fibers. The remaining amount determines how the linen feels against the skin and how it reacts to industrial dyes.
Waxes on the outer surface provide a natural water repellent effect and contribute to the characteristic luster of the fabric.
Finishing Constraint
Precise removal of these elements through scouring and bleaching is necessary for high quality finishing. If too many of the non-cellulosic components remain, the fabric will be harsh and resistant to color uptake. Over-processing, however, can strip away the lignin that provides structural strength, leading to a weak and flimsy cloth.
Mills must find the exact point where the fiber is clean enough for the buyer’s needs without compromising the natural durability of the linen. Monitoring the weight loss during chemical treatment provides a direct measure of how much of this material has been removed.