Chemical Finishing
An industrial finishing process utilizes anhydrous liquid ammonia at sub-zero temperatures to modify the crystalline structure of cellulose in linen fabrics. Applying liquid ammonia treatment transforms cellulose I into cellulose III, which relieves internal stresses in the flax fibres. This treatment improves the dimensional stability, crease resistance and softness of the woven cloth.
It is applied to woven linen fabrics after bleaching and before final dyeing or finishing.
Structural Modification
The interaction of liquid ammonia with flax causes the cell walls to swell, which eliminates the irregular twists and bends of the natural fibres. In a typical sequence at a Chinese finishing mill, the dry fabric is passed through a sealed chamber of liquid ammonia at approximately minus thirty-three degrees Celsius before the ammonia is rapidly evaporated using hot water or steam. This rapid removal of the solvent prevents the recrystallization of cellulose back to its rigid form, resulting in a fabric with a soft handle and excellent wrinkle recovery.
Because the process is carried out in a closed system, up to ninety-nine percent of the ammonia is recovered and reused, reducing chemical waste.
Fabric Performance
Finishing mills record the processed fabric weight and shrinkage rate to verify the success of the treatment. Treated fabrics are tested against the buyer’s specifications for shrinkage and tear strength before being approved for export. This chemical modification ensures the fabric retains its smooth surface after multiple washes.